Jolie and Aniston, who were both previously married to Brad Pitt, rarely attend the same events but this year's award ceremony will see the two ladies handing out the trophy to the winners.
Other stars who will be presenting at the event include Hugh Grant, Isabelle Huppert, Ricky Martin, Penelope Cruz, Seth Rogen, Kerry Washington, Gal Gadot and Kelly Clarkson.
Amy Poehler, Neil Patrick Harris, Sharon Stone, Alicia Vikander, Sarah Jessica Parker, Chris Hemsworth, 'Game of Thrones' stars Kit Harington and Emilia Clarke, Emma Watson, and Halle Berry are also among the big names who will give out prizes.
This year's ceremony will be hosted by Seth Meyers. (ANI)