The other four people, named in warrants, are Toni Comin, Clara Ponsati, Lluis Puig and Meritxell Serret.
The charges include sedition, rebellion, misuse of funds, abuse of authority and contempt.
Puigdemont and the 13 former ministers were ordered to appear before the Spanish high court. Of the nine former officials who showed up, eight were detained and one was freed on bond, the report further said.
Puigdemont didn't appear, but issued a video message in which he called the court's action "an attack on democracy."
According to the reports, the sacked Catalan leader is considering standing in a snap election in the region on December 21.
Catalonia unilaterally declared independence and Madrid responded by suspending the region's autonomy, sacking the government and imposing direct rule.
Before Madrid's imposition of direct rule over it, Catalonia enjoyed wide autonomy, including control over its own policing, education and healthcare.
Catalan nationalists have always argued that the region is a separate nation with its own history, culture and language, and that it should have increased fiscal independence. (ANI)